Smells like plastic melting/burning?

First thought would be a plastic bag that you ran over and it caught on your exhaust pipe. I have had that happen before.

Check the catalytic converter after the car has been running to make sure that it is not red hot, and overheating something nearby.

If it were coming from the engine area, I would suspect synthetic oil leaking. I have found that synthetic motor oil smells like burning plastic when it burns on the exhaust manifold.