RAV4 2013 Emission test fail

Good ideas above. I’m guessing a fuel trim test has already been done, suggest to ask your shop for that data and post it here. It would be hard to believe a shop would remove the cylinder head and clean the tops of the pistons without first doing a fuel trim test.

If the fuel trim tests says the fuel mixture is too rich, likely causes are

  • Engine coolant temp sensor is faulty (perhaps this is actually the “water pressure sensor” referenced by OP)
  • Fuel rail pressure is too high
  • Fuel injector(s) leaking
  • MAF sensor is faulty or dirty
  • Engine air filter clogged
  • Evap system problem, especially purge valve
  • O2 sensor faulty
  • Exhaust system not flowing freely
  • Engine cylinder compression is too low (internal engine problem)

Higher octane fuel is unlikely to help. Suggest to give up on that idea. A fuel injector cleaning procedure or treatment might help though. It doesn’t pertain to the exactly same problem, but it might still be helpful to read through the following thread.