Which of these 2 cars would be better to buy between this 2014 Camry or the 2020 Camry?

Of those two, I’d choose the 2020. I purchased my used truck at one year old, turned out to be a good choice. The sweet spot for used cars is around 3-5 years imo. So before making an offer on a 2020 at that price, suggest to check the rental car agency used car lots for comparisons.