If you have the alignment printout try posting the specs as given and let’s take a look at them.
The steering wheel being off-center is often the result of a worn, or more than likely bent, suspension component such as a lower control arm. A curb strike, bad pothole, rough railroad track, etc. could be responsible for this.
The toe in/out may not be the problem except indirectly; the camber or caster being off due to a worn/bent part will alter the toe.